Knowledge Management System of Northwest Institute of Plateau Biology, CAS
Wet-chemistry topotactic synthesis of bimetallic iron-nickel sulfide nanoarrays: an advanced and versatile catalyst for energy efficient overall water and urea electrolysis | |
Zhu, Wenxin1; Yue, Zhihao1; Zhang, Wentao1; Hu, Na2; Luo, Zhengtao1; Ren, Meirong1; Xu, Zhijie1; Wei, Ziyi1; Suo, Yourui2; Wang, Jianlong1 | |
2018-03-14 | |
发表期刊 | JOURNAL OF MATERIALS CHEMISTRY A |
卷号 | 6期号:10页码:4346-4353 |
文章类型 | Article |
摘要 | In this study, we report that bimetallic iron-nickel sulfide nanowall arrays supported on nickel foam (Fe-11.1%-Ni3S2/Ni foam) via wet-chemistry conversion from its LDH precursor could perform the function of a high-performance and versatile catalyst toward both overall water and urea electrolysis in a base. Its efficiency for overall water splitting is superior to those of most newly reported transition metal-based bifunctional catalysts, with small cell voltage of 1.60 V needed to gain 10 mA cm(-2). Moreover, this electrode also performs well toward the UOR, requiring very small potentials of 0.284 and 0.372 V (vs. SCE) to achieve 10 and 100 mA cm(-2) in 1.0 M KOH with 0.33 M urea. After replacing the anodic OER with the UOR that has a much lower thermodynamic voltage, this urea-mediated water-electrolysis device could sustain an overall current density of 10 mA cm(-2) at a low voltage of only 1.46 V (140 mV less than that for its urea-free counterpart) for over 20 h. Also, battery-and solar energy-assisted overall water and urea electrolysis devices were built to explore the viability of future less-energy-intensive and large-scale hydrogen generation. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1039/c7ta10584c |
关键词[WOS] | HYDROGEN EVOLUTION REACTION ; OXYGEN-EVOLUTION ; HIGHLY EFFICIENT ; BIFUNCTIONAL ELECTROCATALYSTS ; NANOWIRE ARRAYS ; NANOSHEET ARRAY ; NI FOAM ; OXIDATION ; ALKALINE ; ROBUST |
收录类别 | SCI |
语种 | 英语 |
项目资助者 | National Natural Science Foundation of China(21675127) ; Fundamental Research Funds for the Northwest A&F University of China(2014YB093 ; Development Project of Qinghai Key Laboratory(2017-ZJ-Y10) ; 2452015257) |
WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
WOS类目 | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
WOS记录号 | WOS:000428847300013 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://210.75.249.4/handle/363003/13361 |
专题 | 中国科学院西北高原生物研究所 |
作者单位 | 1.Northwest A&F Univ, Coll Food Sci & Engn, Yangling 712100, Shaanxi, Peoples R China 2.Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Key Lab Qinghai Tibet Plateau Biol Resour, Xining 810008, Qinghai, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, Wenxin,Yue, Zhihao,Zhang, Wentao,et al. Wet-chemistry topotactic synthesis of bimetallic iron-nickel sulfide nanoarrays: an advanced and versatile catalyst for energy efficient overall water and urea electrolysis[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(10):4346-4353. |
APA | Zhu, Wenxin.,Yue, Zhihao.,Zhang, Wentao.,Hu, Na.,Luo, Zhengtao.,...&Wang, Jianlong.(2018).Wet-chemistry topotactic synthesis of bimetallic iron-nickel sulfide nanoarrays: an advanced and versatile catalyst for energy efficient overall water and urea electrolysis.JOURNAL OF MATERIALS CHEMISTRY A,6(10),4346-4353. |
MLA | Zhu, Wenxin,et al."Wet-chemistry topotactic synthesis of bimetallic iron-nickel sulfide nanoarrays: an advanced and versatile catalyst for energy efficient overall water and urea electrolysis".JOURNAL OF MATERIALS CHEMISTRY A 6.10(2018):4346-4353. |
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