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Quaternary ammonium-functionalized MCM-48 mesoporous silica as a sorbent for the dispersive solid-phase extraction of endocrine disrupting compounds in water
Zhang, Shijuan1,2; Lu, Fengli1,2; Ma, Xiaoyun1,2; Yue, Mingbo1,2; Li, Yanxin1,2; Liu, Jiammin1,2; You, Jinmao1,2,3
2018-07-06
Source PublicationJOURNAL OF CHROMATOGRAPHY A
ISSN0021-9673
Volume1557Pages:1-8
SubtypeArticle
AbstractMCM-48 mesoporous silica was functionalized with dimethyloctadecyl[3-(dimethoxysilyl)propyl]ammonium chloride, a quaternary ammonium salt with a long hydrophobic chain, to prepare a new sorbent for the dispersive solid-phase extraction (DSPE) of seven endocrine disrupting compounds (EDCs) including 4-hexylphenol, 4-octylphenol, 4-nonylphenol, bisphenol A, estrone, 17 beta-estradiol and estriol in water. A series of differently functionalized MCM-48 materials were also synthesized, and they served as reference materials to study the mechanism. The developed DSPE method was combined with HPLC with fluorescence detection to evaluate the adsorption performance. The results indicated that the quaternary ammonium-functionalized MCM-48 mesoporous silica can be used as ideal sorbent for EDCs in water with recoveries of higher than 95% due to the electrostatic interactions and hydrophobic effect. Hydrogen bonding and pi-pi interactions in other synthesized materials could lead to about 25-30% increase in recoveries, but the results for polyhydroxy compounds were still not satisfying. The quaternary ammonium-functionalized MCM-48 mesoporous silica was successfully applied to the DSPE of EDCs in real water samples. The optimum extraction conditions were sorbent amount, 15 mg; desorption time; 5 min; elution volume, 0.8 mL; sample pH 3.0; and salt addition, 5 g/L. The limits of detection were in the range of 1.2-2.6 ng/L, while the limits of quantitation were in the range of 4.3-8.3 ng/L. (C) 2018 Elsevier B.V. All rights reserved.
KeywordMcm-48 Dispersive Solid-phase Extraction Endocrine Disrupting Compounds Quaternary Ammonium Salt
WOS HeadingsScience & Technology ; Life Sciences & Biomedicine ; Physical Sciences
DOI10.1016/j.chroma.2018.05.011
WOS KeywordPERFORMANCE LIQUID-CHROMATOGRAPHY ; QUADRUPOLE-MASS-SPECTROMETRY ; PERFLUORINATED CARBOXYLIC-ACIDS ; ENVIRONMENTAL WATER ; RISK-ASSESSMENT ; BISPHENOL-A ; ORGANIC FRAMEWORK ; PHTHALATE-ESTERS ; SENSITIVE METHOD ; AQUEOUS-MEDIA
Indexed BySCI
Language英语
Funding OrganizationNatural Science Foundation of Shandong Province(ZR2018MC031) ; National Science Foundation of China(21475075) ; National Undergraduate Training Program for Innovation and Entrepreneurship of China(201710446036)
WOS Research AreaBiochemistry & Molecular Biology ; Chemistry
WOS SubjectBiochemical Research Methods ; Chemistry, Analytical
WOS IDWOS:000433651500001
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://210.75.249.4/handle/363003/13821
Collection中国科学院西北高原生物研究所
Corresponding AuthorYue, Mingbo; You, Jinmao
Affiliation1.Qufu Normal Univ, Shandong Prov Key Lab Life Organ Anal, Qufu, Peoples R China
2.Qufu Normal Univ, Key Lab Pharmaceut Intermediates & Anal Nat Med, Qufu, Peoples R China
3.Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining, Qinghai, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Shijuan,Lu, Fengli,Ma, Xiaoyun,et al. Quaternary ammonium-functionalized MCM-48 mesoporous silica as a sorbent for the dispersive solid-phase extraction of endocrine disrupting compounds in water[J]. JOURNAL OF CHROMATOGRAPHY A,2018,1557:1-8.
APA Zhang, Shijuan.,Lu, Fengli.,Ma, Xiaoyun.,Yue, Mingbo.,Li, Yanxin.,...&You, Jinmao.(2018).Quaternary ammonium-functionalized MCM-48 mesoporous silica as a sorbent for the dispersive solid-phase extraction of endocrine disrupting compounds in water.JOURNAL OF CHROMATOGRAPHY A,1557,1-8.
MLA Zhang, Shijuan,et al."Quaternary ammonium-functionalized MCM-48 mesoporous silica as a sorbent for the dispersive solid-phase extraction of endocrine disrupting compounds in water".JOURNAL OF CHROMATOGRAPHY A 1557(2018):1-8.
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