Knowledge Management System of Northwest Institute of Plateau Biology, CAS
| Determination of phthalate esters in environmental water by magnetic Zeolitic Imidazolate Framework-8 solid-phase extraction coupled with high-performance liquid chromatography | |
| Liu, Xiaomei1; Sun, Zhiwei1; Chen, Guang1; Zhang, Wanwan1; Cai, Yiping1; Kong, Rongmei1; Wang, Xiaoyan2; Suo, Yourui2; You, Jinmao1,2,3 | |
| 2015-08-28 | |
| 发表期刊 | JOURNAL OF CHROMATOGRAPHY A
 |
| 卷号 | 1409页码:46-52 |
| 文章类型 | Article |
| 摘要 | In this study, the magnetic Zeolitic Imidazolate Framework-8 (ZIF-8) microspheres were successfully synthesized and applied as an effective sorbent for preconcentration of several typical phthalate esters (PAEs) from environmental water samples. Firstly, the solvothermal treatment method was used for preparation of Fe3O4 nanoparticles. Then, mercaptoacetic acid (MAA) was served as the functionalized chemical to modify Fe3O4 nanoparticles. The Fe3O4@ZIF-8 core-shell microspheres were synthesized through coating the MAA-capped Fe3O4 nanoparticles with ZIF-8. By coupling magnetic solid-phase extraction (MSPE) with high-performance liquid chromatography (HPLC), a reliable, sensitive and cost-effective method for simultaneous determination of five main PAEs including dimethyl phthalate (DMP), diethyl phthalate (DEP), di-n-butyl phthalate (DBP), benzyl butyl phthalate (BBP), and dioctyl phthalate (DOP) was developed. Good linearity was observed in the range of 1.0-100.0 mu g/L. The limits of detection (S/N =3) and limits of quantification (S/N = 10) were in the range of 0.08-0.24 and 0.3-0.8 mu g/L, respectively. The relative standard deviations were less than 5.5% and the accuracies of the method for the PAEs were in the range from 85.6% to 103.6%. Finally, the Fe3O4@ZIF-8 was successfully applied for rapid extraction of trace amounts of PAEs in environmental water samples. (C) 2015 Elsevier B.V. All rights reserved.; In this study, the magnetic Zeolitic Imidazolate Framework-8 (ZIF-8) microspheres were successfully synthesized and applied as an effective sorbent for preconcentration of several typical phthalate esters (PAEs) from environmental water samples. Firstly, the solvothermal treatment method was used for preparation of Fe3O4 nanoparticles. Then, mercaptoacetic acid (MAA) was served as the functionalized chemical to modify Fe3O4 nanoparticles. The Fe3O4@ZIF-8 core-shell microspheres were synthesized through coating the MAA-capped Fe3O4 nanoparticles with ZIF-8. By coupling magnetic solid-phase extraction (MSPE) with high-performance liquid chromatography (HPLC), a reliable, sensitive and cost-effective method for simultaneous determination of five main PAEs including dimethyl phthalate (DMP), diethyl phthalate (DEP), di-n-butyl phthalate (DBP), benzyl butyl phthalate (BBP), and dioctyl phthalate (DOP) was developed. Good linearity was observed in the range of 1.0-100.0 mu g/L. The limits of detection (S/N =3) and limits of quantification (S/N = 10) were in the range of 0.08-0.24 and 0.3-0.8 mu g/L, respectively. The relative standard deviations were less than 5.5% and the accuracies of the method for the PAEs were in the range from 85.6% to 103.6%. Finally, the Fe3O4@ZIF-8 was successfully applied for rapid extraction of trace amounts of PAEs in environmental water samples. (C) 2015 Elsevier B.V. All rights reserved. |
| 关键词 | Magnetic Solid-phase Extraction (Mspe) Zeolitic Lmidazolate Framework-8 (Zif-8) High-performance Liquid Chromatography (Hplc) Phthalate Esters (Paes) |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences |
| 关键词[WOS] | POLYCYCLIC AROMATIC-HYDROCARBONS ; MASS-SPECTROMETRY ; MILK SAMPLES ; ACID-ESTERS ; MS ANALYSIS ; PORE-WALLS ; MICROEXTRACTION ; NANOPARTICLES ; MICROSPHERES ; ENRICHMENT |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| WOS类目 | Biochemical Research Methods ; Chemistry, Analytical |
| WOS记录号 | WOS:000359882600005 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://210.75.249.4/handle/363003/5523 |
| 专题 | 中国科学院西北高原生物研究所 |
| 作者单位 | 1.Qufu Normal Univ, Key Lab Life Organ Anal Shandong Prov, Qufu 273165, Peoples R China 2.Chinese Acad Sci, Northwest Inst Plateau Biol, Xining, Peoples R China 3.Key Lab Pharmaceut Intermediates & Nat Prod, Qufu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiaomei,Sun, Zhiwei,Chen, Guang,et al. Determination of phthalate esters in environmental water by magnetic Zeolitic Imidazolate Framework-8 solid-phase extraction coupled with high-performance liquid chromatography[J]. JOURNAL OF CHROMATOGRAPHY A,2015,1409:46-52. |
| APA | Liu, Xiaomei.,Sun, Zhiwei.,Chen, Guang.,Zhang, Wanwan.,Cai, Yiping.,...&You, Jinmao.(2015).Determination of phthalate esters in environmental water by magnetic Zeolitic Imidazolate Framework-8 solid-phase extraction coupled with high-performance liquid chromatography.JOURNAL OF CHROMATOGRAPHY A,1409,46-52. |
| MLA | Liu, Xiaomei,et al."Determination of phthalate esters in environmental water by magnetic Zeolitic Imidazolate Framework-8 solid-phase extraction coupled with high-performance liquid chromatography".JOURNAL OF CHROMATOGRAPHY A 1409(2015):46-52. |
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