Biosorption of azo dyes by raspberry-like Fe3O4@yeast magnetic microspheres and their efficient regeneration using heterogeneous Fenton-like catalytic processes over an up-flow packed reactor

NWIPB OpenIR

	Biosorption of azo dyes by raspberry-like Fe3O4@yeast magnetic microspheres and their efficient regeneration using heterogeneous Fenton-like catalytic processes over an up-flow packed reactor
	Song, Rui 1; Bai, Bo 2; Puma, Gianluca Li 3; Wang, Honglun 2; Suo, Yourui 2
	2015-08-01
发表期刊	REACTION KINETICS MECHANISMS AND CATALYSIS
卷号	115 期号:2 页码:547-562
文章类型	Article
摘要	Raspberry-like Fe3O4@yeast composite microspheres, whose properties integrate the biosorption features of yeast cells with the excellent magnetic and catalytic properties of Fe3O4 nanoparticles, were synthesized by a simple electrostatic-interaction-driven self-assembly heterocoagulation. They were successfully applied in an up-flow packed column for the removal of the model water contaminant methylene blue dye (MB) by consecutive bioadsorption-heterogeneous Fenton oxidation cycles. The as-synthesized Fe3O4@yeast composites were characterized by field emission scanning electron microscopy, energy-dispersive spectroscopy (EDS), powder X-ray diffraction and Fourier transform infrared spectroscopy. The adsorption process was controlled by the electrostatic interactions between the adsorbent and contaminant. The adsorbent is suitable for the adsorption of positively charged compounds at mildly acidic pH, neutral and alkaline pH, with the highest performance observed at alkaline pH. The experimental breakthrough curves measured at different influent MB concentration, flow rate, bed height and pH were modeled by the Yoon-Nelson model. The in situ regeneration of the contaminant-loaded Fe3O4@yeast microspheres and their reuse in multiple cycles was demonstrated by triggering the heterogeneous Fenton-like reaction catalyzed by the supported magnetite. The raspberry-like Fe3O4@yeast magnetic microsphere should be a promising and practical adsorbent for removal and destruction of positively charged organic compounds in wastewater.; Raspberry-like Fe3O4@yeast composite microspheres, whose properties integrate the biosorption features of yeast cells with the excellent magnetic and catalytic properties of Fe3O4 nanoparticles, were synthesized by a simple electrostatic-interaction-driven self-assembly heterocoagulation. They were successfully applied in an up-flow packed column for the removal of the model water contaminant methylene blue dye (MB) by consecutive bioadsorption-heterogeneous Fenton oxidation cycles. The as-synthesized Fe3O4@yeast composites were characterized by field emission scanning electron microscopy, energy-dispersive spectroscopy (EDS), powder X-ray diffraction and Fourier transform infrared spectroscopy. The adsorption process was controlled by the electrostatic interactions between the adsorbent and contaminant. The adsorbent is suitable for the adsorption of positively charged compounds at mildly acidic pH, neutral and alkaline pH, with the highest performance observed at alkaline pH. The experimental breakthrough curves measured at different influent MB concentration, flow rate, bed height and pH were modeled by the Yoon-Nelson model. The in situ regeneration of the contaminant-loaded Fe3O4@yeast microspheres and their reuse in multiple cycles was demonstrated by triggering the heterogeneous Fenton-like reaction catalyzed by the supported magnetite. The raspberry-like Fe3O4@yeast magnetic microsphere should be a promising and practical adsorbent for removal and destruction of positively charged organic compounds in wastewater.
关键词	Yeast Iron Oxide Fixed-bed Fenton-like Reaction Regeneration Wastewater
WOS标题词	Science & Technology ; Physical Sciences
关键词[WOS]	METHYLENE-BLUE ADSORPTION ; HYDROGEN-PEROXIDE ; CARBON ; NANOPARTICLES ; KINETICS ; REMOVAL ; MODEL ; HYDROXYAPATITES ; DEGRADATION ; MECHANISM
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000358170200010
引用统计	被引频次：14[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/5529
专题	中国科学院西北高原生物研究所
作者单位	1.Changan Univ, Coll Environm Sci & Engn, Xian 710054, Peoples R China 2.Chinese Acad Sci, Northwest Plateau Inst Biol, Xining 810001, Peoples R China 3.Univ Loughborough, Dept Chem Engn, Environm Nanocatalysis & Photoreact Engn, Loughborough LE11 3TU, Leics, England
推荐引用方式 GB/T 7714	Song, Rui,Bai, Bo,Puma, Gianluca Li,et al. Biosorption of azo dyes by raspberry-like Fe3O4@yeast magnetic microspheres and their efficient regeneration using heterogeneous Fenton-like catalytic processes over an up-flow packed reactor[J]. REACTION KINETICS MECHANISMS AND CATALYSIS,2015,115(2):547-562.
APA	Song, Rui,Bai, Bo,Puma, Gianluca Li,Wang, Honglun,&Suo, Yourui.(2015).Biosorption of azo dyes by raspberry-like Fe3O4@yeast magnetic microspheres and their efficient regeneration using heterogeneous Fenton-like catalytic processes over an up-flow packed reactor.REACTION KINETICS MECHANISMS AND CATALYSIS,115(2),547-562.
MLA	Song, Rui,et al."Biosorption of azo dyes by raspberry-like Fe3O4@yeast magnetic microspheres and their efficient regeneration using heterogeneous Fenton-like catalytic processes over an up-flow packed reactor".REACTION KINETICS MECHANISMS AND CATALYSIS 115.2(2015):547-562.

条目包含的文件		下载所有文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
Song-2015-Biosorptio（886KB）			开放获取	CC BY-NC-SA	浏览下载