Knowledge Management System of Northwest Institute of Plateau Biology, CAS
Adsorption Performance of Methyl Violet via alpha-Fe2O3@Porous Hollow Carbonaceous Microspheres and Its Effective Regeneration through a Fenton-Like Reaction | |
Tong, Zhiqing1; Zheng, Pei1; Bai, Bo1,2; Wang, Honglun2; Suo, Yourui2 | |
2016-04-01 | |
发表期刊 | CATALYSTS |
卷号 | 6期号:4 |
文章类型 | Article |
摘要 | alpha-Fe2O3@porous hollow carbonaceous microspheres (alpha-Fe2O3@PHCMs) were prepared through a combination of hydrothermal and calcination method. The novel alpha-Fe2O3@PHCMs integrated the adsorptive and catalytic performances and served as an inexpensive adsorbent to rapidly remove cationic dye (methyl violet (MV)) from aqueous solution. Equilibrium studies indicated that the dye molecules obeyed Langmuir type of adsorption with the calculated maximum adsorption capacity of 539.8 mg.g(-1) at 313.15 K. Kinetic data were better described by pseudo-second-order model and the thermodynamic studies illustrated that MV adsorption onto the composite was spontaneous, endothermic and occurred by physisorption. The Fenton-like process was found to be effective for the regeneration of the spent alpha-Fe2O3@PHCMs. The regeneration efficiency, as high as 88.0%, was still maintained after three consecutive adsorption-regeneration cycles. FTIR and XRD characterizations of the composite before and after adsorption-regeneration treatment showed that the Fenton-like process did not cause serious damage to the structure of composites. |
关键词 | Alpha-fe2o3@porous Hollow Carbonaceous Microspheres Methyl Violet Equilibrium Isotherm Kinetics Thermodynamics |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.3390/catal6040058 |
关键词[WOS] | AQUEOUS-SOLUTION ; BASIC DYE ; REMOVAL ; EQUILIBRIUM ; ADSORBENT ; COMPOSITE ; SORPTION ; WATER ; ACID ; BLUE |
收录类别 | SCI |
语种 | 英语 |
项目资助者 | National Natural Science Foundation of China(21176031) ; Shanxi Provincial Natural Science Foundation of China(2015JM2071) ; China Scholarship Council (CSC)(201506560012) ; FundamentalResearch Funds for the Central Universities-Excellent Doctoral Dissertation Cultivation Project of Chang'an University(310829150004) ; Fundamental Research Funds for the Central Universities(310829162014 ; 310811160211) |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000375210900010 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://210.75.249.4/handle/363003/5744 |
专题 | 中国科学院西北高原生物研究所 |
作者单位 | 1.Changan Univ, Coll Environm Sci & Engn, Xian 710054, Peoples R China 2.Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810001, Peoples R China |
推荐引用方式 GB/T 7714 | Tong, Zhiqing,Zheng, Pei,Bai, Bo,et al. Adsorption Performance of Methyl Violet via alpha-Fe2O3@Porous Hollow Carbonaceous Microspheres and Its Effective Regeneration through a Fenton-Like Reaction[J]. CATALYSTS,2016,6(4). |
APA | Tong, Zhiqing,Zheng, Pei,Bai, Bo,Wang, Honglun,&Suo, Yourui.(2016).Adsorption Performance of Methyl Violet via alpha-Fe2O3@Porous Hollow Carbonaceous Microspheres and Its Effective Regeneration through a Fenton-Like Reaction.CATALYSTS,6(4). |
MLA | Tong, Zhiqing,et al."Adsorption Performance of Methyl Violet via alpha-Fe2O3@Porous Hollow Carbonaceous Microspheres and Its Effective Regeneration through a Fenton-Like Reaction".CATALYSTS 6.4(2016). |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论