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Synthesis, structure and properties of a new polyiodide compound with the 1D -> 3D interdigitated architecture | |
Yu, Hao-Long; He, Yuan-Chun; Zhao, Fang-Hua; Wang, Yan; Wang, Ai-Ning; Hao, Meng-Ge; Si, Zhen-Shu; You, Jinmao | |
2019 | |
发表期刊 | POLYHEDRON |
卷号 | 169 |
摘要 | A new polyiodide compound [Ni(bpy)(3)(H2O)(2)]center dot bpy center dot 2H(2)O center dot 2I(3)(-) (1), where bpy is 4,4'-bipyridine, has been synthesized by hydrothermal method. In 1, the adjacent Ni(11) ions are bridged with the bpy ligand to form a 1D chain, which is further extended to be a 3D supramolecular framework by pi-pi interactions. This 3D supramolecular framework is a rare 1D -> 3D interdigitated architecture. Compound 1 has been characterized by X-ray crystallography, elemental analysis, IR, PXRD and TG. The variable-temperature magnetic studies indicate very weak antiferromagnetic interactions in 1. (C) 2019 Elsevier Ltd. All rights reserved. |
关键词 | Coordination compound Crystal structure Ni(II) Iodine Magnetic |
文献类型 | 期刊论文 |
条目标识符 | http://210.75.249.4/handle/363003/59718 |
专题 | 中国科学院西北高原生物研究所 |
推荐引用方式 GB/T 7714 | Yu, Hao-Long,He, Yuan-Chun,Zhao, Fang-Hua,et al. Synthesis, structure and properties of a new polyiodide compound with the 1D -> 3D interdigitated architecture[J]. POLYHEDRON,2019,169. |
APA | Yu, Hao-Long.,He, Yuan-Chun.,Zhao, Fang-Hua.,Wang, Yan.,Wang, Ai-Ning.,...&You, Jinmao.(2019).Synthesis, structure and properties of a new polyiodide compound with the 1D -> 3D interdigitated architecture.POLYHEDRON,169. |
MLA | Yu, Hao-Long,et al."Synthesis, structure and properties of a new polyiodide compound with the 1D -> 3D interdigitated architecture".POLYHEDRON 169(2019). |
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