1D Water cages in a double-walled framework based on cubic [Ni-4(mu(3)-OH)(4)] units: Synthesis, structure, and magnetism

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	1D Water cages in a double-walled framework based on cubic [Ni-4(mu(3)-OH)(4)] units: Synthesis, structure, and magnetism
	Zhao, Fang-Hua; Li, Zhong-Lin; He, Yuan-Chun; Huang, Long-Wei; Jia, Xin-Meng; Yan, Xiao-Qing; Wang, Yu-Fei; You, Jin-Mao
	2019
发表期刊	JOURNAL OF SOLID STATE CHEMISTRY
卷号	271
摘要	The hydrothermal reaction of NiSO4 center dot 6H(2)O and 4,4'-bis(1-imidazolyl)bipheny (bibp) has afforded a new nickel complex, {[Ni-4(mu(3)-OH)(4)(mu(4)-SO4)(bibp)(4)](OH)(2)center dot 12H(2)O}(n) (1). The Ni(II) centers are bridged by mu(3)-OH- anions into cubic [Ni-4(mu(3)-OH)(4)] units, which are connected by bibp ligands and mu(4)-SO42- anions into a double-walled 3D framework with channels along c direction. Unusual 1D water cages with a repeat of vase-like water cluster are trapped in the channels. Magnetic studies reveal ferromagnetic behavior for complex 1, and the thermal property of 1 was also studied.
关键词	Cubic Ni-4 units 1D water cages Magnetism
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/59843
专题	中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	Zhao, Fang-Hua,Li, Zhong-Lin,He, Yuan-Chun,et al. 1D Water cages in a double-walled framework based on cubic [Ni-4(mu(3)-OH)(4)] units: Synthesis, structure, and magnetism[J]. JOURNAL OF SOLID STATE CHEMISTRY,2019,271.
APA	Zhao, Fang-Hua.,Li, Zhong-Lin.,He, Yuan-Chun.,Huang, Long-Wei.,Jia, Xin-Meng.,...&You, Jin-Mao.(2019).1D Water cages in a double-walled framework based on cubic [Ni-4(mu(3)-OH)(4)] units: Synthesis, structure, and magnetism.JOURNAL OF SOLID STATE CHEMISTRY,271.
MLA	Zhao, Fang-Hua,et al."1D Water cages in a double-walled framework based on cubic [Ni-4(mu(3)-OH)(4)] units: Synthesis, structure, and magnetism".JOURNAL OF SOLID STATE CHEMISTRY 271(2019).