A highly sensitive and selective method for determination of phenoxy carboxylic acids from environmental water samples by dispersive solid-phase extraction coupled with ultra high performance liquid chromatography-tandem mass spectrometry

NWIPB OpenIR

	A highly sensitive and selective method for determination of phenoxy carboxylic acids from environmental water samples by dispersive solid-phase extraction coupled with ultra high performance liquid chromatography-tandem mass spectrometry
	Ji, Zhongyin; Cheng, Jie; Song, Cuihua; Hu, Na; Zhou, Wu; Suo, Yourui; Sun, Zhiwei; You, Jinmao
	2019
发表期刊	TALANTA
卷号	191
摘要	A rapid and efficient method for extraction of 12 phenoxy carboxylic acids (PCAs) in environmental water samples was established based on metal organic framework MIL-101 assisted dispersive solid phase extraction (DSPE). 12 PCAs were labeled by d(0)-10-methyl-2-(piperazin-1-ylsulfonyflanthracen-9(10H)-one(d(0)-MASPz) and d(3)-10-methyl-2-(piperazin-1-ylsulfonypanthracen-9(10H)-one(d(3)-MASPz), allowing each analyte to have an isotope internal standard. A stable isotope-coded strategy for the detection of 12 PCAs was developed under optimized extraction conditions and UHPLC-MS/MS conditions. All PCAs analytes were in good linearity in the concentration range of 5-1000 ng/L, and the calibration function was verified by the Mandel fitting test with a 95% confidence level. The LODs and LOQs were estimated by the IUPACs recommendations. The LODs ranged from 0.18 to 0.88 ng/L, and LOQs ranged from 0.59 to 2.90 ng/L. The intra-day and inter-day precision in three spiked levels (5, 50 and 100 ng/L) were in the range of (1.40 +/- 0.14) %- (2.76 +/- 0.12) % and (2.60 +/- 0.26) % (3.83 +/- 0.32) %, respectively. The developed method has been successfully applied to the determination of PCAs in environmental water samples with recoveries ranging from 95.3% to 105.5%. All of the precision and recovery analyses were done in triplicate.
关键词	Isotope-coded derivatization Dispersive solid-phase extraction Ultra-high performance liquid chromatography-tandem mass spectrometry Phenoxy carboxylic acid
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/59909
专题	中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	Ji, Zhongyin,Cheng, Jie,Song, Cuihua,et al. A highly sensitive and selective method for determination of phenoxy carboxylic acids from environmental water samples by dispersive solid-phase extraction coupled with ultra high performance liquid chromatography-tandem mass spectrometry[J]. TALANTA,2019,191.
APA	Ji, Zhongyin.,Cheng, Jie.,Song, Cuihua.,Hu, Na.,Zhou, Wu.,...&You, Jinmao.(2019).A highly sensitive and selective method for determination of phenoxy carboxylic acids from environmental water samples by dispersive solid-phase extraction coupled with ultra high performance liquid chromatography-tandem mass spectrometry.TALANTA,191.
MLA	Ji, Zhongyin,et al."A highly sensitive and selective method for determination of phenoxy carboxylic acids from environmental water samples by dispersive solid-phase extraction coupled with ultra high performance liquid chromatography-tandem mass spectrometry".TALANTA 191(2019).