Magnetic covalent organic frameworks based on magnetic solid phase extraction for determination of six steroidal and phenolic endocrine disrupting chemicals in food samples

NWIPB OpenIR

	Magnetic covalent organic frameworks based on magnetic solid phase extraction for determination of six steroidal and phenolic endocrine disrupting chemicals in food samples
	Li, Ning; Wu, Di; Liu, Jichao; Hu, Na; Shi, Xuexiang; Dai, Chunji; Sun, Zhiwei; Suo, Yourui; Li, Guoliang; Wu, Yongning
	2018
发表期刊	MICROCHEMICAL JOURNAL
卷号	143
摘要	A simple and rapid magnetic covalent organic frameworks based on magnetic solid phase extraction method was proposed for effective determination of six steroidal and phenolic endocrine disrupting chemicals in meat samples. Fluorescence labeling combined with high performance liquid chromatography fluorescence detection was used to quantify endocrine disrupting chemicals. Covalent organic frameworks could be a wonderful choice as sorbent for endocrine disrupting chemicals enrichment due to its characteristics of large specific surface area, great structure stability and functional properties. In this work, COF(TpBD) was chosen as functionalized groups to be grafted onto the surface of Fe3O4 microspheres via one-step surface fabrication strategy. The parameters affecting the extraction efficiency were investigated in detail. The adsorption equilibrium was achieved within 5 min. Under the optimized conditions, the obtained Fe3O4@COF(TpBD) materials showed excellent extraction performance for endocrine disrupting chemicals with high sensitivity (1.4-8.7 mu g L-1 for LODs and 4.6-29.0 mu g L-1 for LOQs) and good linearity (R >= 0.9986). Determination of endocrine disrupting chemicals in meats was achieved using the proposed method. Furthermore, the method, validated on spiked meats (including chicken, pork and shrimp), showed satisfactory accuracy, with average recoveries in the 89.6-108.9% range and relative standard deviations 6.3%. Additionally, two kinetic models were investigated to recognize the target analytes adsorption mechanism onto Fe3O4@COF(TpBD) materials, and the results indicated that the pseudo second -order model was the most suitable in describing the adsorption kinetics of endocrine disrupting chemicals on the Fe3O4@COF(TpBD) materials. The proposed method was proved to be feasible for the determination of endocrine disrupting chemicals in complex food samples.
关键词	Endocrine disrupting chemicals Magnetic covalent organic frameworks Magnetic solid phase extraction High performance liquid chromatography Food samples
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/59929
专题	中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	Li, Ning,Wu, Di,Liu, Jichao,et al. Magnetic covalent organic frameworks based on magnetic solid phase extraction for determination of six steroidal and phenolic endocrine disrupting chemicals in food samples[J]. MICROCHEMICAL JOURNAL,2018,143.
APA	Li, Ning.,Wu, Di.,Liu, Jichao.,Hu, Na.,Shi, Xuexiang.,...&Wu, Yongning.(2018).Magnetic covalent organic frameworks based on magnetic solid phase extraction for determination of six steroidal and phenolic endocrine disrupting chemicals in food samples.MICROCHEMICAL JOURNAL,143.
MLA	Li, Ning,et al."Magnetic covalent organic frameworks based on magnetic solid phase extraction for determination of six steroidal and phenolic endocrine disrupting chemicals in food samples".MICROCHEMICAL JOURNAL 143(2018).