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Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to alpha-aminophosphine oxides | |
Huang, Qiang; Zhu, Lei; Yi, Dong; Zhao, Xiaohui; Wei, Wei | |
2020 | |
发表期刊 | CHINESE CHEMICAL LETTERS |
卷号 | 31期号:2 |
摘要 | A new silver mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides for the construction of alpha-aminophosphine oxides has been developed. The C-N and C-P bond could be efficiently formed in one pot operation via sequential C-C and C-O bond cleavage of propargylic alcohols. This present methodology, which not only provides a simple and alternative strategy for the synthesis of alpha-aminophosphine oxides, but also opens a new window for the cleavage reactions of propargyl alcohols via dealkynalation coupling. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved. |
关键词 | Silver Aminophosphinoylation C-C bond cleavage Propargylic alcohols alpha-Aminophosphine oxides |
文献类型 | 期刊论文 |
条目标识符 | http://210.75.249.4/handle/363003/60426 |
专题 | 中国科学院西北高原生物研究所 |
推荐引用方式 GB/T 7714 | Huang, Qiang,Zhu, Lei,Yi, Dong,et al. Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to alpha-aminophosphine oxides[J]. CHINESE CHEMICAL LETTERS,2020,31(2). |
APA | Huang, Qiang,Zhu, Lei,Yi, Dong,Zhao, Xiaohui,&Wei, Wei.(2020).Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to alpha-aminophosphine oxides.CHINESE CHEMICAL LETTERS,31(2). |
MLA | Huang, Qiang,et al."Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to alpha-aminophosphine oxides".CHINESE CHEMICAL LETTERS 31.2(2020). |
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