Syntheses and magnetic properties of three transition metal complexes based on 4 '-p-tolyl-2,2 ':6 ',2 ''-terpyridine and SCN-

NWIPB OpenIR

	Syntheses and magnetic properties of three transition metal complexes based on 4 '-p-tolyl-2,2 ':6 ',2 ''-terpyridine and SCN-
	Zhao, Fang-Hua; Jia, Xin-Meng; He, Yuan-Chun; Huang, Long-Wei; Yan, Xiao-Qing; Li, Zhong-Lin; Li, Jia-Xing; Feng, Rui; You, Jin-Mao
	2019
发表期刊	POLYHEDRON
卷号	173
摘要	Three transition metal complexes based on 4'-p-tolyl-2,2':6',2 ''-terpyridine (ttpy) and SCN-, [Mn-2(ttpy)(2)(SCN)(3)Cl](1), [Co-2(ttpy)(2)(SCN4]center dot H2O (2) and [Ni(ttpy)(SCN)(2)](2) (3), have been hydrothermally synthesized. The single-crystal X-ray diffraction analyses reveal that the three complexes display discrete molecules with three distinct structures caused by the different coordination geometry of the transition metal centers. Complex 1 contains two neutral independent components of mononuclear [Mn(ttpy)(SCN)(2)] and binuclear [Mn(ttpy)(SCN)Cl](2). Complex 2 shows an ion-pair bicomponent structure of [Co(ttpy)(2)](2+) and [Co(SCN)(4)](2-). Complex 3 shows a binuclear structure bridged by two end-to-end bridging SCN- anions. Magnetic properties of the three complexes have been investigated. (C) 2019 Elsevier Ltd. All rights reserved.
关键词	Terpyridine ligand Transition metal complexes SCN- Crystal structure Magnetic property
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/60493
专题	中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	Zhao, Fang-Hua,Jia, Xin-Meng,He, Yuan-Chun,et al. Syntheses and magnetic properties of three transition metal complexes based on 4 '-p-tolyl-2,2 ':6 ',2 ''-terpyridine and SCN-[J]. POLYHEDRON,2019,173.
APA	Zhao, Fang-Hua.,Jia, Xin-Meng.,He, Yuan-Chun.,Huang, Long-Wei.,Yan, Xiao-Qing.,...&You, Jin-Mao.(2019).Syntheses and magnetic properties of three transition metal complexes based on 4 '-p-tolyl-2,2 ':6 ',2 ''-terpyridine and SCN-.POLYHEDRON,173.
MLA	Zhao, Fang-Hua,et al."Syntheses and magnetic properties of three transition metal complexes based on 4 '-p-tolyl-2,2 ':6 ',2 ''-terpyridine and SCN-".POLYHEDRON 173(2019).