Hyperacmosin N, new acylphloroglucinol derivative with complicated caged core from Hypericum acmosepalum

NWIPB OpenIR

	Hyperacmosin N, new acylphloroglucinol derivative with complicated caged core from Hypericum acmosepalum
	Sun, Ming-xia; Dang, Jun; Zhu, Ting-ting; Wang, Xue; Suo, Xin-yue; Wang, Jia-jia; Ji, Teng-fei; Liu, Bo
	2021
发表期刊	TETRAHEDRON
卷号	94
摘要	Three new polycyclic polyprenylated acylphloroglucinol derivatives, hyperacmosins N -P (1-3), were isolated from the air-dried aerial parts of Hypericum asmosepalum. Especially, compound 1 possessed a rare hex acyclic core, which was formed via oxidation and radical cyclization. Their structures were established by NMR, HRMS (ESI), and experimental electronic circular dichroism (ECD) spectra. The plausible biogenetic pathways of 1-3 were proposed, which gave an insight for future biomimetic synthesis of the novel compounds. (c) 2021 Elsevier Ltd. All rights reserved.
关键词	Hypericum acmosepalum PPAPs Hexacyclic skeleton Radical cyclization
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/60746
专题	中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	Sun, Ming-xia,Dang, Jun,Zhu, Ting-ting,et al. Hyperacmosin N, new acylphloroglucinol derivative with complicated caged core from Hypericum acmosepalum[J]. TETRAHEDRON,2021,94.
APA	Sun, Ming-xia.,Dang, Jun.,Zhu, Ting-ting.,Wang, Xue.,Suo, Xin-yue.,...&Liu, Bo.(2021).Hyperacmosin N, new acylphloroglucinol derivative with complicated caged core from Hypericum acmosepalum.TETRAHEDRON,94.
MLA	Sun, Ming-xia,et al."Hyperacmosin N, new acylphloroglucinol derivative with complicated caged core from Hypericum acmosepalum".TETRAHEDRON 94(2021).