Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air

NWIPB OpenIR

	Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air
	Liu, Ruisheng; Liu, Qishun; Meng, Haoran; Ding, Hongyu; Hao, Jindong; Ji, Zhongyin; Yue, Huilan; Wei, Wei
	2021
发表期刊	ORGANIC CHEMISTRY FRONTIERS
卷号	8 期号:9
摘要	A metal-free and visible-light-promoted strategy has been achieved for the construction of alpha-ketoesters via aerobic oxidation of alpha-diazoesters with dioxygen in air at room temperature. Using cheap, readily available Eosin Y as the photocatalyst and O-2(air) as the green oxidant, the present protocol offers a mild and efficient approach to a wide range of alpha-ketoesters in moderate to good yields. Preliminary mechanistic studies suggested that photo-excited singlet oxygen was involved in the present reaction system.
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/60807
专题	中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	Liu, Ruisheng,Liu, Qishun,Meng, Haoran,et al. Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air[J]. ORGANIC CHEMISTRY FRONTIERS,2021,8(9).
APA	Liu, Ruisheng.,Liu, Qishun.,Meng, Haoran.,Ding, Hongyu.,Hao, Jindong.,...&Wei, Wei.(2021).Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air.ORGANIC CHEMISTRY FRONTIERS,8(9).
MLA	Liu, Ruisheng,et al."Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air".ORGANIC CHEMISTRY FRONTIERS 8.9(2021).