Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates

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	Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates
	Lv, YF; Luo, JY; Ma, YC; Dong, Q; He, L
	2021
发表期刊	ORGANIC CHEMISTRY FRONTIERS
卷号	8 期号:11 页码:2461
摘要	A new visible-light-mediated protocol has been proposed for the synthesis of thiosulfonates via metal-free sulfonylation of thiols with aryldiazonium and sodium metabisulphite at room temperature. This mild three-component reaction simply utilizes readily available rhodamine 6G as the photocatalyst and cheap inorganic sulfite of sodium metabisulfite as a SO2 surrogate and provides an attractive strategy to access various unsymmetrical thiosulfonates in moderate to good yields under oxidant- or strong acid-free conditions. Preliminary mechanistic studies indicated that a radical pathway was involved in the present transformation.
收录类别	SCIE
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/61378
专题	中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	Lv, YF,Luo, JY,Ma, YC,et al. Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates[J]. ORGANIC CHEMISTRY FRONTIERS,2021,8(11):2461.
APA	Lv, YF,Luo, JY,Ma, YC,Dong, Q,&He, L.(2021).Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates.ORGANIC CHEMISTRY FRONTIERS,8(11),2461.
MLA	Lv, YF,et al."Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates".ORGANIC CHEMISTRY FRONTIERS 8.11(2021):2461.