Copper-catalyzed highly selective direct hydrosulfonylation of alkynes with arylsulfinic acids leading to vinyl sulfones

NWIPB OpenIR

	Copper-catalyzed highly selective direct hydrosulfonylation of alkynes with arylsulfinic acids leading to vinyl sulfones
	Wei, Wei 1,2; Li, Jinli 1,2; Yang, Daoshan 1,2; Wen, Jiangwei 1,2; Jiao, Yueting 1,2; You, Jinmao 1,2,3; Wang, Hua 1,2
	2014
发表期刊	ORGANIC & BIOMOLECULAR CHEMISTRY
ISSN	1477-0520
卷号	12 期号:12 页码:1861-1864
文章类型	Article
摘要	A novel Cu-catalyzed direct hydrosulfonylation of alkynes with arylsulfinic acids for the synthesis of (E)-vinyl sulfones has been realized under mild conditions with 100% atom efficiency. The present protocol provides an attractive approach to various vinyl sulfones in good to excellent yields, with the advantages of operation simplicity, atom economy, and high stereo-and regioselectivities.; A novel Cu-catalyzed direct hydrosulfonylation of alkynes with arylsulfinic acids for the synthesis of (E)-vinyl sulfones has been realized under mild conditions with 100% atom efficiency. The present protocol provides an attractive approach to various vinyl sulfones in good to excellent yields, with the advantages of operation simplicity, atom economy, and high stereo-and regioselectivities.
WOS标题词	Science & Technology ; Physical Sciences
关键词[WOS]	TERMINAL ALKYNES ; ENANTIOMERICALLY PURE ; CONJUGATE ADDITION ; INTERNAL ALKYNES ; CARBOXYLIC-ACIDS ; ALKENES ; ARYL ; INHIBITORS ; SULFOXIDES ; AMINES
收录类别	SCI ; CCR
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000332225900003
引用统计	被引频次：98[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/4282
专题	中国科学院西北高原生物研究所
作者单位	1.Qufu Normal Univ, Key Lab Life Organ Anal, Qufu 273165, Peoples R China 2.Qufu Normal Univ, Key Lab Pharmaceut Intermediates & Anal Nat Med, Qufu 273165, Peoples R China 3.Chinese Acad Sci, Northwest Inst Plateau Biol, Xining 810001, Peoples R China
推荐引用方式 GB/T 7714	Wei, Wei,Li, Jinli,Yang, Daoshan,et al. Copper-catalyzed highly selective direct hydrosulfonylation of alkynes with arylsulfinic acids leading to vinyl sulfones[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2014,12(12):1861-1864.
APA	Wei, Wei.,Li, Jinli.,Yang, Daoshan.,Wen, Jiangwei.,Jiao, Yueting.,...&Wang, Hua.(2014).Copper-catalyzed highly selective direct hydrosulfonylation of alkynes with arylsulfinic acids leading to vinyl sulfones.ORGANIC & BIOMOLECULAR CHEMISTRY,12(12),1861-1864.
MLA	Wei, Wei,et al."Copper-catalyzed highly selective direct hydrosulfonylation of alkynes with arylsulfinic acids leading to vinyl sulfones".ORGANIC & BIOMOLECULAR CHEMISTRY 12.12(2014):1861-1864.