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Metal- and photocatalyst-free visible-light-promoted regioselective selenylation of coumarin derivatives via oxidation-induced C-H functionalization
Yang, Daoshan; Li, Guoqing; Xing, Chengyu; Cui, Wenwen; Li, Kexin; Wei, Wei
2018
发表期刊ORGANIC CHEMISTRY FRONTIERS
卷号5期号:20
摘要A visible-light-promoted approach for the regioselective selenylation of 4-amino substituted coumarins has been developed under metal- and photocatalyst-free conditions at room temperature. Notably, dual selenylation products were also obtained selectively when N-substituted 4-(phenylamino)-2H-chromen-2-ones were employed. Preliminary mechanism studies suggest that oxidation-induced C-H functionalization may be involved in this transformation. The present method provides a highly attractive and alternative approach to C-Se bond formation.
文献类型期刊论文
条目标识符http://210.75.249.4/handle/363003/59951
专题中国科学院西北高原生物研究所
推荐引用方式
GB/T 7714
Yang, Daoshan,Li, Guoqing,Xing, Chengyu,et al. Metal- and photocatalyst-free visible-light-promoted regioselective selenylation of coumarin derivatives via oxidation-induced C-H functionalization[J]. ORGANIC CHEMISTRY FRONTIERS,2018,5(20).
APA Yang, Daoshan,Li, Guoqing,Xing, Chengyu,Cui, Wenwen,Li, Kexin,&Wei, Wei.(2018).Metal- and photocatalyst-free visible-light-promoted regioselective selenylation of coumarin derivatives via oxidation-induced C-H functionalization.ORGANIC CHEMISTRY FRONTIERS,5(20).
MLA Yang, Daoshan,et al."Metal- and photocatalyst-free visible-light-promoted regioselective selenylation of coumarin derivatives via oxidation-induced C-H functionalization".ORGANIC CHEMISTRY FRONTIERS 5.20(2018).
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