Gas Purge Microsyringe Extraction Coupled with Dispersive Liquid-Liquid Microextraction for the Determination of Acidic Compounds in Food Packaging Materials

doi:10.1007/s12161-016-0660-x

NWIPB OpenIR

	Gas Purge Microsyringe Extraction Coupled with Dispersive Liquid-Liquid Microextraction for the Determination of Acidic Compounds in Food Packaging Materials
	Zhang, Shijuan 1; Sheng, Cuncun 1; Zhang, Jiangchunzi 1; Li, Yanxin 1; You, Jinmao 1,2
	2017-05-01
发表期刊	FOOD ANALYTICAL METHODS
卷号	10 期号:5 页码:1164-1171
文章类型	Article
摘要	A green, simple and sensitive method was developed for the analysis of volatile carboxylic acids (VFAs) and perfluorocarboxylic acids (PFCAs) in food packaging materials. The acidic compounds in food packaging materials were first extracted by gas purge microsyringe extraction (GP-MSE) with 1.0 mL 0.1 mol center dot L-1 NaOH solution, then the analytes were dispersive liquid-liquid microextracted (DLLME) by 50 mu L chloroform as extraction solvent and 200 mu L acetonitrile as dispersive solvent. The 2-(5-Benzoacridine) ethyl-p-toluenesulfonate (BAETS) with excellent fluorescence property was applied to enhance the high performance liquid chromatography (HPLC) sensitivity. The obtained recoveries for the VFAs ranged from 92.0 to 101 %. The method LODs calculated at a signal-to-noise ratio (S/N) of 3 were in the range of 0.80-3.40 mu g center dot kg(-1), while the LOQs calculated at S/N of 10 were in the range of 2.5-10.2 mu g center dot kg(-1). All compounds were in good linearity with concentration coefficients of higher than 0.997. Perfluorooctanoic acid (PFOA) was found in all of the 15 kinds of samples analyzed with concentrations ranging from 4.86-7.56 mu g center dot kg(-1). Acetic acid, butyric acid, and caprylic acid were found in half of the samples analyzed. The other analytes were also found in more than 30 % samples with concentrations varied between 3.96 and 293 mu g center dot kg(-1).
关键词	Acidic Compounds Food Packaging Materials Gp-mse Hplc
WOS标题词	Science & Technology ; Life Sciences & Biomedicine
DOI	10.1007/s12161-016-0660-x
关键词[WOS]	GREEN ANALYTICAL-CHEMISTRY ; FATTY-ACIDS ; MASS-SPECTROMETRY ; CHROMATOGRAPHY ; MIGRATION ; PLASTICIZERS ; WATER
收录类别	SCI
语种	英语
项目资助者	National Science Foundation of China(21,275,089) ; Natural Science Foundation of Shandong Province(ZR2014BQ009)
WOS研究方向	Food Science & Technology
WOS类目	Food Science & Technology
WOS记录号	WOS:000399014600004
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/6817
专题	中国科学院西北高原生物研究所
作者单位	1.Qufu Normal Univ, Shandong Prov Key Lab Life Organ Anal, Qufu, Peoples R China 2.Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Shijuan,Sheng, Cuncun,Zhang, Jiangchunzi,et al. Gas Purge Microsyringe Extraction Coupled with Dispersive Liquid-Liquid Microextraction for the Determination of Acidic Compounds in Food Packaging Materials[J]. FOOD ANALYTICAL METHODS,2017,10(5):1164-1171.
APA	Zhang, Shijuan,Sheng, Cuncun,Zhang, Jiangchunzi,Li, Yanxin,&You, Jinmao.(2017).Gas Purge Microsyringe Extraction Coupled with Dispersive Liquid-Liquid Microextraction for the Determination of Acidic Compounds in Food Packaging Materials.FOOD ANALYTICAL METHODS,10(5),1164-1171.
MLA	Zhang, Shijuan,et al."Gas Purge Microsyringe Extraction Coupled with Dispersive Liquid-Liquid Microextraction for the Determination of Acidic Compounds in Food Packaging Materials".FOOD ANALYTICAL METHODS 10.5(2017):1164-1171.