NWIPB OpenIR
Layered vanadium(IV) disulfide nanosheets as a peroxidase-like nanozyme for colorimetric detection of glucose
Huang, Lunjie1; Zhu, Wenxin1; Zhang, Wentao1; Chen, Kai1; Wang, Jing1; Wang, Rong1; Yang, Qingfeng1; Hu, Na2; Suo, Yourui2; Wang, Jianlong1
2018
发表期刊MICROCHIMICA ACTA
ISSN0026-3672
卷号185期号:1
文章类型Article
摘要The authors have discovered that vanadium disulfide (VS2) nanosheets, synthesized by a hydrothermal method, exert stable peroxidase-like activity. The catalytic activity, with H2O2 as a cosubstrate, follows Michaelis-Menten kinetics and varies with temperature, pH value and H2O2 concentration. Two-dimensional VS2 sheets acting as peroxidase (POx) mimics can replace horseradish peroxidase due to their availability, robustness, and reusability. The POx-like activity of VS2 sheets was exploited to design a colorimetric glucose assay by using 3,3', 5,5'-tetramethylbenzidine as a substrate and by working at an analytical wavelength of 652 nm. The assay covers the 5 to 250 mu M glucose concentration range with a 1.5 mu M detection limit. It was applied to the analysis of glucose in fruit juice. In our perception, the peroxidase-like nanozyme out of the family of transition metal dichalcogenides presented here has a wide scope in that it may stimulate promising biocatalytic applications in biotechnology and analytical chemistry.
关键词Food Analysis Nanocatalysts Optical Tmb Oxidation Transition Metal Dichalcogenides
WOS标题词Science & Technology ; Physical Sciences
DOI10.1007/s00604-017-2552-1
关键词[WOS]HYDROGEN EVOLUTION REACTION ; HORSERADISH-PEROXIDASE ; ARTIFICIAL ENZYMES ; CATALYTIC-ACTIVITY ; VISUAL DETECTION ; MOS2 NANOSHEETS ; NANOPARTICLES ; NANOMATERIALS ; MECHANISM ; OXYGEN
收录类别SCI
语种英语
项目资助者National Natural Science Foundation of China(21675127) ; Fundamental Research Funds for the Northwest A&F University of China(2014YB093 ; Development Project of Qinghai Key Laboratory(2017-ZJ-Y10) ; 2452015257)
WOS研究方向Chemistry
WOS类目Chemistry, Analytical
WOS记录号WOS:000422691200063
出版者SPRINGER WIEN
引用统计
被引频次:88[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://210.75.249.4/handle/363003/13290
专题中国科学院西北高原生物研究所
通讯作者Wang, Jianlong
作者单位1.Northwest A&F Univ, Coll Food Sci & Engn, Yangling 712100, Shaanxi, Peoples R China
2.Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Key Lab Qinghai Tibet Plateau Biol Resour, Xining 810008, Qinghai, Peoples R China
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GB/T 7714
Huang, Lunjie,Zhu, Wenxin,Zhang, Wentao,et al. Layered vanadium(IV) disulfide nanosheets as a peroxidase-like nanozyme for colorimetric detection of glucose[J]. MICROCHIMICA ACTA,2018,185(1).
APA Huang, Lunjie.,Zhu, Wenxin.,Zhang, Wentao.,Chen, Kai.,Wang, Jing.,...&Wang, Jianlong.(2018).Layered vanadium(IV) disulfide nanosheets as a peroxidase-like nanozyme for colorimetric detection of glucose.MICROCHIMICA ACTA,185(1).
MLA Huang, Lunjie,et al."Layered vanadium(IV) disulfide nanosheets as a peroxidase-like nanozyme for colorimetric detection of glucose".MICROCHIMICA ACTA 185.1(2018).
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