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Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to alpha-aminophosphine oxides
Huang, Qiang; Zhu, Lei; Yi, Dong; Zhao, Xiaohui; Wei, Wei
2020
发表期刊CHINESE CHEMICAL LETTERS
卷号31期号:2
摘要A new silver mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides for the construction of alpha-aminophosphine oxides has been developed. The C-N and C-P bond could be efficiently formed in one pot operation via sequential C-C and C-O bond cleavage of propargylic alcohols. This present methodology, which not only provides a simple and alternative strategy for the synthesis of alpha-aminophosphine oxides, but also opens a new window for the cleavage reactions of propargyl alcohols via dealkynalation coupling. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
关键词Silver Aminophosphinoylation C-C bond cleavage Propargylic alcohols alpha-Aminophosphine oxides
文献类型期刊论文
条目标识符http://210.75.249.4/handle/363003/60426
专题中国科学院西北高原生物研究所
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GB/T 7714
Huang, Qiang,Zhu, Lei,Yi, Dong,et al. Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to alpha-aminophosphine oxides[J]. CHINESE CHEMICAL LETTERS,2020,31(2).
APA Huang, Qiang,Zhu, Lei,Yi, Dong,Zhao, Xiaohui,&Wei, Wei.(2020).Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to alpha-aminophosphine oxides.CHINESE CHEMICAL LETTERS,31(2).
MLA Huang, Qiang,et al."Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to alpha-aminophosphine oxides".CHINESE CHEMICAL LETTERS 31.2(2020).
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